Question
Chlorine dioxide, $\mathrm{ClO}_{2},$ reacts with fluorine to give a new gas that contains $\mathrm{Cl}$, $\mathrm{O}$, and $\mathrm{F}$. In an experiment, you find that $0.150 \mathrm{g}$ of this new gas has a pressure of $17.2 \mathrm{mm}$ Hg in a $1850-\mathrm{mL}$. flask at $21^{\circ} \mathrm{C} .$ What is the identity of the unknown gas?
Chlorine dioxide, $\mathrm{ClO}_{2},$ reacts with fluorine to give a new gas that contains $\mathrm{Cl}$, $\mathrm{O}$, and $\mathrm{F}$. In an experiment, you find that $0.150 \mathrm{g}$ of this new gas has a pressure of $17.2 \mathrm{mm}$ Hg in a $1850-\mathrm{mL}$. flask at $21^{\circ} \mathrm{C} .$ What is the identity of the unknown gas?
Chemistry 101
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Chlorine gas reacts with fluorine gas to form chlorine trifluoride:
A 2.00-L reaction vessel, initially at 298 K, contains chlorine gas at a partial pressure of 337 mmHg and fluorine gas at a partial pressure of 729 mmHg. Identify the limiting reactant and determine the theoretical yield of ClF3 in grams.
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FAQs
Does chlorine dioxide react with plastic? ›
Results show that ClO2 has a deep effect on all the materials tested (plastics and metals) and that severe damage occurs due to its strong oxidizing power in terms of surface chemical modification of metals and progressive cracking of plastics.
What is the reaction of ClO2 and F2? ›The reaction between fluorine and chlorine dioxide, F2(g) + ClO2(g) → 2FClO2(g) Proceeds according to the following rate Law: r=k⋅PF2⋅PClO2 where k= 0.0489 bar-1 s-1.
Is chlorine dioxide the same as bleach? ›Chlorine dioxide is used as a bleach at pulp mills, which make paper and paper products, and in public water-treatment facilities, to make water safe for drinking. It has also been used to decontaminate public buildings. Chlorine dioxide is soluble in water and will react rapidly with other compounds.
What is chlorine dioxide tablets used for? ›Chlorine dioxide kills bacteria, viruses, and fungi. Very small amounts are used in public water treatment facilities. At high doses, it can damage red blood cells and the lining of the gastrointestinal (GI) tract.
What is the reaction of fluorine with chlorine dioxide? ›The overall reaction is: F2 + ClO2 + F + ClO2 —> FClO2 + F + FClO2…
What are the harmful effects of chlorine dioxide? ›* Breathing Chlorine Dioxide can irritate the lungs causing coughing and/or shortness of breath. Higher exposures can cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of breath.
What are the dangers of chlorine dioxide? ›Short-term Exposure: Chlorine dioxide may cause irritation of the eyes, nose, throat, and lungs. It may produce coughing, wheezing, and severe breathing difficulties which may be delayed in onset. 2. Long-term Exposure: Repeated exposure to chlorine dioxide may cause chronic bronchitis.
What is the reaction of Cl2 and O2? ›Answer and Explanation: The equation of reaction given is: Cl2(g)+2O2(g)→2ClO2(g) C l 2 ( g ) + 2 O 2 ( g ) → 2 C l O 2 ( g ) .
What is the product of reaction H2 O2 and Cl2? ›When Hydrogen peroxide H 2 O 2 reacts with Chlorine , it forms Hydrochloric acid and Oxygen gas .
What type of reaction is Cl2 +H2? ›Explanation : Two elements H2 and Cl2 combine to from a single compound, HCl. Hence, it is a combination reaction As two elements combine to from a compound, it is an element - element combination. Was this answer helpful?
Is chlorine dioxide safe in water? ›
Chlorine dioxide is a safe form of water treatment. It is used in various applications, including the treatment of drinking water for human consumption.
Is chlorine dioxide safe in mouthwash? ›Great for long-term use: Mouthwash with chlorine dioxide is safe and non-toxic and can be used long-term with no unwanted side effects like tissue sloughing, teeth staining or tartar buildup.
Is chlorine dioxide safe for cleaning? ›Chlorine dioxide is a safe and effective disinfectant, even at concentrations as low as 20 to 30 mg/L.
What are the benefits of drinking chlorine dioxide solution? ›Uses & Benefits
Chlorine dioxide is a disinfectant. When added to drinking water, it helps destroy bacteria, viruses and some types of parasites that can make people sick, such as Cryptosporidium parvum and Giardia lamblia.
Chlorine dioxide is considered potentially toxic to humans at concentrations higher than 0.8 mg/L.
Do hospitals use chlorine dioxide? ›Procedure. Chlorine Dioxide treatment may be used as a secondary disinfectant in hospitals and other facilities due to the effectiveness of chlorine dioxide in controlling pathogens such as Legionella pneumophila, Stenotrophomonas maltophilia, and Mycobacterium avium complex.
Does chlorine dioxide react with stainless steel? ›Fact: Our pure chlorine dioxide DOES NOT corrode stainless steel. Stainless steels can be corroded by the acidic byproducts generated along with other manufacturer's chlorine dioxide products. Fact: Chlorine dioxide gas is safe on most electronics.
What happens to chlorine dioxide in water? ›Chlorine dioxide is soluble in water and will react rapidly with other compounds. When it reacts in water, chlorine dioxide forms chlorite ion, which is also a very reactive chemical. Because chlorine dioxide is very reactive, it is able to kill bacteria and microorganisms in water.
What does fluorine react badly with? ›Fluorine even combines with the noble gases, krypton, xenon, and radon. Even in dark, cool conditions, fluorine reacts explosively with hydrogen. It is so reactive that glass, metals, and even water, as well as other substances, burn with a bright flame in a jet of fluorine gas.
How long does chlorine dioxide stay in the body? ›About 43% of orally administered chlorine dioxide is eliminated in the urine and feces within 72 h. It is not excreted via the lungs.
Is chlorine dioxide carcinogenic? ›
Based on inadequate information in humans and in animals, the International Agency for Research on Cancer (IARC) and the EPA have determined that chlorine dioxide and sodium chlorite are not classifiable as to human carcinogenicity.
Is chlorine dioxide the same as hydrogen peroxide? ›Hydrogen peroxide is a strong oxidizer. In fact, it is more potent than chlorine (Cl2), chlorine dioxide (ClO2), and potassium permanganate (KMnO4). Also, through catalysis, hydrogen peroxide can be converted into hydroxyl radicals (OH).
How do you get rid of chlorine dioxide? ›Chlorine dioxide does not hydrolyze when it enters water; it remains a dissolved gas in solution. Chlorine dioxide is approximately 10 times more soluble in water than chlorine. Chlorine dioxide can be removed by aeration or carbon dioxide.
What can chlorine gas do to your lungs? ›Inhalation of higher concentrations of chlorine gas (>15 ppm) can rapidly lead to respiratory distress with airway constriction and accumulation of fluid in the lungs (pulmonary edema). Patients may have immediate onset of rapid breathing, blue discoloration of the skin, wheezing, rales or hemoptysis.
How much chlorine dioxide in drinking water? ›Background and Existing Drinking Water Standards
A federal drinking water standard (MRDL) for chlorine dioxide of 0.8 mg/L was established by US EPA in its Stage 1 Disinfectants and Disinfectants Byproducts Rule in 1998. The MCL for the byproduct, chlorite is 1.0 mg/L.
Despite having several oxides, chlorine won't react directly with oxygen. Argon doesn't react either. Sodium burns in chlorine with a bright orange flame. White solid sodium chloride is produced.
What happens when chlorine and Sulphur dioxide react in water? ›The heat of oxidation of aqueous sulfur dioxide with gaseous chlorine has been determined by calorimetric methods. The results correspond to the reaction: Cl 2 ( g ) + SO 2 ⋅ 2500 H 2 O + 2502 H 2 O = H 2 SO 4 ⋅ 2500 H 2 O + 2 ( HCl ⋅ 1250 H 2 O ) , Δ H ( 25 ° C ) = − 77.28 ± 0.14 kcal / mole .
What is the reaction of o2? ›On heating, oxygen enters into a reaction with various simple substances (metals and non-metals), forming oxides as a result of interaction – compounds of elements with oxygen. The interaction of chemical elements with oxygen is called the oxidation reaction.
What reaction is h2 Cl2 → 2HCl? ›Answer:the answer is Combination Reaction.
What type of reaction is this 2 h2o → o2 2 h2? ›The molecules of water (H2O) are split and molecules of hydrogen gas (H2) and oxygen gas (O2) are formed. 2. You are performing a chemical reaction by mixing two liquids together.
What is the balanced equation for Cl2+ h2o2? ›
H2O2+Cl2→2HCl+O2.
Is H2 Cl2 → 2HCl endothermic or exothermic? ›H2(g) + Cl2(g)⟶ 2HCl(g) + 185 kJ . This reaction is exothermic.
Is H2 +Cl2 a redox reaction? ›So, H2 has been oxidised and Cl2 has been reduced, making this a redox reaction.
Is it OK to drink CO2 water? ›No evidence suggests that carbonated or sparkling water is bad for you. It's not that harmful to dental health, and it seems to have no effect on bone health. Interestingly, a carbonated drink may even enhance digestion by improving swallowing ability and reducing constipation.
What are the disadvantages of chlorine dioxide water treatment? ›Chlorine Dioxide; Disadvantages
If not controlled carefully, this can lead to untreated chlorite or excessive amounts of chlorine in the treated water. It can also lead to the formation of chlorate or chlorinated disinfection by-products.
“While soda and other carbonated drinks have been associated with negative health effects, carbonation is not harmful in and of itself,” says Saima Lodhi, MD, an internal medicine doctor at Scripps Coastal Medical Center Hillcrest. Drinking plain carbonated water has some health benefits, she adds.
Does chlorine dioxide whiten teeth? ›Conclusion: Chlorine dioxide whitens teeth at a faster rate than hydrogen peroxide.
Why does my breath smell bad even after I brush? ›Cavities and gum disease
The bacteria that cause bad breath can hide in cavities in your teeth. This makes it difficult to get rid of the bacteria when you're brushing your teeth because it's hidden in places that you can't reach. Similarly, these bacteria can hide in deep pockets caused by gum disease.
Gargling with hydrogen peroxide may ease discomfort by reducing the number of bacteria in the mouth and helping clear the infection. Hydrogen peroxide may help kill bacteria by releasing oxygen, which alters the environment of anaerobic bacteria and inhibits their growth.
What foods contain chlorine dioxide? ›Prawns, canned tuna, scallops, called salmon, raw oysters, mussels, lobster, crab and cod all provide significant amounts of chloride to your diet. Ham, bacon, corned beef, organ meats, salami and sausages are also high in chloride.
Which is better chlorine or chlorine dioxide? ›
Chlorine and chlorine dioxide are both oxidising agents (electron receivers). However, chlorine has the capacity to take in two electrons, whereas chlorine dioxide can absorb five. This means that, mole for mole, ClO2 is 2.6 times more effective than chlorine.
What are the benefits of chlorine in the body? ›It helps to regulate the amount of fluid and types of nutrients going in and out of the cells. It also maintains proper pH levels, stimulates stomach acid needed for digestion, stimulates the action of nerve and muscle cells, and facilitates the flow of oxygen and carbon dioxide within cells.
What are two uses of chlorine dioxide? ›Uses. Chlorine dioxide is used for bleaching of wood pulp and for the disinfection (called chlorination) of municipal drinking water, treatment of water in oil and gas applications, disinfection in the food industry, microbiological control in cooling towers, and textile bleaching.
Does chlorine dioxide really work? ›Chlorine dioxide kills bacteria, viruses, and fungi. Very small amounts are used in public water treatment facilities. At high doses, it can damage red blood cells and the lining of the gastrointestinal (GI) tract.
Is chlorine dioxide an antibiotic? ›Chlorine Dioxide Is a Size-Selective Antimicrobial Agent.
What is the best material for chlorine dioxide? ›Best Chemical Resistant Gaskets for Chlorine Dioxide
Polytetrafluoroethylene (PTFE) is one of the best materials for chemical resistant gaskets. It can withstand almost any substance, including chlorine dioxide.
Hydrochloric and sulphuric acids at some concentrations are particularly aggressive towards stainless steel. General corrosion can be quite destructive and happen to the entire surface at once.
What is the greatest hazard from chlorine dioxide? ›* Breathing Chlorine Dioxide can irritate the lungs causing coughing and/or shortness of breath. Higher exposures can cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of breath.
Can you drink water treated with chlorine dioxide? ›Chlorine dioxide is a safe form of water treatment. It is used in various applications, including the treatment of drinking water for human consumption.
What are the dangers of fluoride? ›► Exposure to Sodium Fluoride can cause nausea, vomiting, diarrhea, abdominal pain, and loss of appetite. twitching, tremors, convulsions, coma and even death. deposit of Fluoride in the bones and teeth, a condition called Fluorosis.
Why is fluorine so toxic? ›
Fluorine as a gas or liquid is not absorbed. The chemical is so highly reactive, however, that it forms other chemicals that can be absorbed. Fluorine forms unstable compounds with oxygen. For example, hydrogen fluoride is the most stable of hydrogen halides and is a very strong acid.
What are the symptoms of fluorine gas poisoning? ›* Repeated exposure can cause nosebleeds, nausea, vomiting, loss of appetite, diarrhea and constipation. * Fluorine may damage the liver and kidneys. * These effects do NOT occur when Fluorine is used to treat drinking water to prevent cavities. * Fluorine is a HIGHLY REACTIVE CHEMICAL and a DANGEROUS EXPLOSION HAZARD.
Does chlorine leach into plastic? ›Yes, it is corrosive to plastic. It does not eat up the plastic in one go (we are assuming you are using the diluted bleach or bleach water as the cleaning agent), but the damage it would create is definite.
What reacts with chlorine dioxide? ›In water, chlorine dioxide reacts quickly to form chlorite ions. When chlorine dioxide reacts with dissolved organic compounds in water-treatment systems, it forms disinfection by-products, such as chlorite and chlorate ions. Like chlorine dioxide, chlorite is very reactive.
Does chlorine dioxide affect stainless steel? ›Fact: Our pure chlorine dioxide DOES NOT corrode stainless steel. Stainless steels can be corroded by the acidic byproducts generated along with other manufacturer's chlorine dioxide products. Fact: Chlorine dioxide gas is safe on most electronics.
What chemicals should be avoided in plastics? ›The chemicals in plastic put our health at risk
Many of the largest and most hazardous chemical families – including heavy metals, flame retardants, phthalates, bisphenols, and fluorinated compounds – are directly associated with plastics production.
Pour bleach into them
Bleach is a powerful, toxic substance that should be used carefully and properly, and pouring it down a drain is not a proper use. Bleach can react with other substances in your pipes, potentially release fumes, and further plug up the system.
Mixing bleach and vinegar creates potentially lethal chlorine gas. If you notice a pungent smell after mixing household cleaners, you should immediately leave the area and try to breathe in fresh air.
Does bleach damage PVC pipes? ›In short, yes. You can safely use bleach to clean and disinfect your PVC pipes, as long as you dilute it first and avoid mixing it with other chemicals.
What is another name for chlorine dioxide? ›Is chlorine dioxide the same as pool chlorine? ›
The key difference between chlorine and chlorine dioxide is that the oxidation state of chlorine atom in chlorine or chlorine gas is zero whereas the oxidation state of chlorine atom in chlorine dioxide is +4.
Does chlorine dioxide affect aluminum? ›The results showed that when the concentration of chlorine dioxide disinfection solution was 200 mg/L, the corrosion degree of aluminum was mild and that of copper was moderate; when the concentration of chlorine dioxide was 400 mg/L, the corrosion degree of A3 steel was severe and that of stainless steel was mild.
What are the disadvantages of chlorine dioxide in water treatment? ›Chlorine Dioxide; Disadvantages
If not controlled carefully, this can lead to untreated chlorite or excessive amounts of chlorine in the treated water. It can also lead to the formation of chlorate or chlorinated disinfection by-products.
The corrosion rate for stainless steel, copper, aluminum, and carbon steel was 0.0000 mm/a, 0.0020 mm/a, 0.0031 mm/a, and 0.0090 mm/a, respectively. Therefore, in addition to having a strong disinfection efficiency, ClO2 gas at < 0.9 mg/m3 was substantially non-corrosive to these metals.
What is the most toxic plastic? ›Polyvinyl chloride, or PVC, is widely known as the most toxic plastic for health and the environment. In its production, it releases dioxins, phthalates, vinyl chloride, ethylene dichloride, lead, cadmium and other toxic chemicals.
What are two of the most toxic chemicals found in plastics? ›The two most important substances to watch out for in plastics are bisphenol A (BPA), used in a variety of consumer products, and certain phthalates, often found in toys.
What plastics should you stay away from? ›Avoid products made from polystyrene (PS #6).
Found in styrofoam food trays, disposable cups and bowls, carry-out containers, and opaque plastic cutlery, polystyrene can leach styrene, a neurotoxin and possible carcinogen.